Cationic monomer‐isomerization oligomerization of 2‐methyl‐1‐butene
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منابع مشابه
Dry Deposition of Biogenic Terpenes via Cationic Oligomerization on Environmental Aqueous Surfaces.
Unraveling the complex interactions between the atmosphere and the biosphere is critical for predicting climate changes. Although it is well-recognized that the large amounts of biogenic volatile organic compounds (BVOCs) emitted by plants must play important roles in this regard, current atmospheric models fail to account for their fate due to missing chemical sinks. Here, we applied online el...
متن کاملOligomerization and regioselective hydrosilylation of styrenes catalyzed by cationic allyl nickel complexes bearing allylphosphine ligands.
The complexes [Ni(eta(3)-CH(2)CHCH(2))Br(kappa(1)P-PR(2)CH(2)CH=CH(2))] (R = Ph 1, (i)Pr2 ) and [Ni(eta(3)-CH(2)C(R')CH(2))(kappa(1)P-PR(2)CH(2)CH=CH(2))(2)][BAr'(4)] (R' = H, R = Ph 4a, R = (i)Pr 4b; R' = CH(3), R = Ph 5a, R = (i)Pr 5b; Ar' = 3,5-C(6)H(3)(CF(3))(2)) have been prepared and characterized. The X-ray crystal structures of 1, 2 and 5b have been determined. 4a-b and 5a-b are catalys...
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The cationic complexes [Ni(eta(3)-CH(2)C(R)CH(2))(SbPh(3))(3)][BAr'(4)] (R = CH(3), H ; Ar' = 3,5-C(6)H(3)(CF(3))(2)), [Ni(eta(3)-CH(2)C(R)CH(2))(AsPh(3))(2)][BAr'(4)] (R = CH(3), H ), [Ni(eta(3)-CH(2)CHCH(2))(PPh(3))(L)][BAr'(4)] (L = SbPh(3), AsPh(3)), and the neutral derivatives [Ni(eta(3)-CH(2)C(R)CH(2))Br(L)] (L = SbPh(3), R = CH(3), H ; L = AsPh(3), R = CH(3), H ) have been prepared and c...
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The distinctive feature of the GroES-GroEL chaperonin system in mediating protein folding lies in its ability to exist in a tetradecameric state, form a central cavity, and encapsulate the substrate via the GroES lid. However, recombinant GroELs of Mycobacterium tuberculosis are unable to act as effective molecular chaperones when expressed in Escherichia coli. We demonstrate here that the inab...
متن کاملControl of Protein Oligomerization and De-oligomerization on Lipid Membranes
Aalto University, P.O. Box 11000, FI-00076 Aalto www.aalto.fi Author Ajay Mahalka Name of the doctoral dissertation Control of Protein Oligomerization and De-oligomerization on Lipid Membranes Publisher School of Science Unit Department of Biomedical Engineering and Computational Science Series Aalto University publication series DOCTORAL DISSERTATIONS 220/2013 Field of research Biomedical Engi...
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ژورنال
عنوان ژورنال: Journal of Polymer Science Part A: Polymer Chemistry
سال: 1996
ISSN: 0887-624X,1099-0518
DOI: 10.1002/(sici)1099-0518(19960915)34:12<2513::aid-pola25>3.3.co;2-z